for what i know, depends on car and their aircond compresor, turning off the a/c can safe up to 20% petrol. and assuming your car have very good aerodynamic, opening the window (didn't mention wether open just 1 window abit or open all window) can waste up to 12% petrol.
but since my car old school toyota, no aerodynamic also so i switch off the a/c whenever i can bear the heat. that mean morning or evening/night when driving alone i dun use a/c.
how much fuel can i safe? not very sure, but just by turning off the a/c everymorning on my way to college, about 7-8km, traffic jam all the time, so take 20-30min at least, already saved me lots of petrol.
before that, i use a/c all the time can go 220-240km for rm40 of petrol. now usually do 250-265km, just by running without a/c everymorning.. ^_^